span{display:block;text-align:left}.mw-parser-output sub.template-chem2-sub{font-size:80%;vertical-align:-0.35em}.mw-parser-output sup.template-chem2-sup{font-size:80%;vertical-align:0.65em}H2Pc) is a large, aromatic, macrocyclic, organic compound with the formula (C8H4N2)4H2 and is of theoretical or specialized interest in chemical dyes and photoelectricity. Google Scholar. 3b bottom panel) using a Tauc plot (FigureS6). 65 ComponentsThis product does not contain any chemicals known to State of California to cause cancer,birth defects, or any other reproductive harm.This product does not contain any chemicals known to State of California to cause cancer,birth defects, or any other reproductive harm. An official website of the United States government. Interested in participating in our Sponsored Content section? [23] and even turf colorants [24]. The rapid thickness change at RH>70% is consistent with formation of a mixed H2O-CuPcTs phase facilitated by hydrogen bonding between H2O adsorbates and gas-phase water molecules16, 17, 38. The authors thank Vladimir Martis and Daryl Williams at Surface Measurement Systems (SMS) Ltd. for their support in development of new testing capability. form = 1.61-1.62 Accosperse cyan blue GT Aqualine blue Bahama blue BC Bermuda blue Blue GLA Blue phthalocyanine .alpha.-form . Interface between an Au (111) Surface and an Ionic Liquid: The Influence of Water on the DoubleLayer Capacitance. The newly synthesized compounds (BS, BS-1, BS-1-CN), copper(II), manganese(III), phthalocyanines (BS-1-Cu, BS-1-Mn) and their water soluble derivatives (BS-1-CuQ, BS-1-MnQ) were characterized by standard methods.All steps of the synthetic procedures were given in Figs. 39, 728732 (2007). As calculated from SPE measurements, the optical film thickness was roughly 50nm when measured at ambient RH. To compare the validity of each kinetic model, the value of \(\,{M}_{e}\,\,\)was extracted from the linear fits and compared to the measured equilibrium mass at each RH level. CuPc belongs to the D4h point group. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. Results indicate that the H2O-CuPcTs interaction can be described by two-step pseudo-first order kinetics. ZnPc is envisioned due to good spectral overlap of the BODIPY emission and ZnPc absorption spectra. Humidity effect on gravimetric properties. Get the most important science stories of the day, free in your inbox. *TCI frequently reviews storage conditions to optimize them. Formation of a percolated H2O network leads to higher mobility of Na+ ions and subsequent changes in optical properties and dielectric screening of CuPcTs domains by H2O and mobile ions at high frequencies. Kadish, K. M., Smith, K. M. & Guilard, R. The Porphyrin Handbook, Applications of Phthalocyanines, vol. 2a. While Ghani et al. Article We studied the interaction of H2O vapor with film of CuPcTs using a multi-modal approach which links gravimetric, broadband dielectric spectroscopy, and DC electrical resistivity measurements. Due to its stability, phthalo blue is also used in inks, coatings, and many plastics. The pigment is insoluble and has no tendency to migrate in the material. 517, 20162022 (2009). Enhanced photocurrent and stability of organic solar cells using solution-based TS-CuPc interfacial layer. [11] Alternatively, heating phthalic anhydride in the presence of urea yields H2Pc. FOIA b8$B "/2y0b?C%-9#Q\X2iDaRh5rEZ@eZJ. The hydrophilic site is associated with the Na+SO3 Insights into the modeling of adsorption isotherm systems. Figure6b shows the CuPcTs-coated and bare gold-coated QCM response to 0.15% RH exposure. Copper phthalocyanine blue Copper tetrabenzoporphyrazine Cromofine blue 4950 Cromophtal blue 4G At RH>60%, water clusters begin to merge, which allows ion diffusion throughout the water-saturated film. Linear fits to the plots of \(t/{M}_{t}\,\,\)vs. \(t\) achieve r2>0.998 inside the entire measured RH range (Fig. 34, 735742 (2000). The phase has a larger overlap and thus, a smaller Cu-Cu spacing (~3.8) compared to the phase (~4.8). Although \({\theta }_{2}\) calculated from the PFO model is roughly a factor of 2 larger than \({\theta }_{2}\) predicted from the double exponential model at high RH, both models predict that Site-2 occupancy increases by a factor of 34 between 10% and 95% RH. The PFO rate equation then becomes \(\,d{M}_{ad}/dt=\,{k}_{1}[{M}_{e}-{M}_{t}]\). Request PDF | Soluble Copper Phthalocyanine Applied for Organic Solar Cells | A soluble derivative of copper phthalocyanine, that is 2,9,16,23-tetra carboxyl copper phthalocyanine (CuTCPc), is . - Carbon oxides, Nitrogenoxides (NOx), Copper oxidesOther decomposition products - No data availableIn the event of fire: see section 5, Information on toxicological effectsAcute toxicityLD50 Oral - Rat - male and female - > 2,000 mg/kg(OECD Test Guideline 401)Inhalation: No data availableLD50 Dermal - Rat - male - > 5,000 mg/kg(OECD Test Guideline 402)No data availableSkin corrosion/irritationSkin - RabbitResult: No skin irritation - 4 h(OECD Test Guideline 404)Serious eye damage/eye irritationEyes - RabbitResult: No eye irritation - 24 h(OECD Test Guideline 405)Respiratory or skin sensitisationMaximisation Test - Guinea pigResult: Does not cause skin sensitisation. Improvement of the photovoltaic parameters of perovskite solar cells using a reduced-graphene-oxide-modified titania layer and soluble copper phthalocyanine as a hole transporter. Muckley ES, Naguib M, Wang HW, Vlcek L, Osti NC, Sacci RL, Sang X, Unocic RR, Xie Y, Tyagi M, Mamontov E, Page KL, Kent PRC, Nanda J, Ivanov IN. [12] Using such methods, approximately 57,000tonnes (63,000Imperial tons) of various phthalocyanines were produced in 1985. (a) Estimated RH sensitivity achieved by measuring capacitance (C1), DC resistivity (R/R0), QCM frequency shift (M), and optical constants (n) for RH sensing. , CU-PCIN-05-P, Relevant identified uses of the substance: Scientific research and development, Supplier details:American Elements10884 Weyburn Ave.Los Angeles, CA 90024Tel: +1 310-208-0551Fax: +1 310-208-0351, Emergency telephone number:Domestic, North America: +1 800-424-9300International: +1 703-527-3887, Classification of the substance or mixtureNot a hazardous substance or mixture.GHS Label elements, including precautionary statementsNot a hazardous substance or mixture.Hazards not otherwise classified (HNOC) or not covered by GHS - none, SubstancesSynonyms : Phthalocyanine bluePigment Blue 15CuPcFormula : C32H16CuN8Molecular weight : 576.07 g/molCAS-No. Exposure to ultra-high vacuum, elevated temperatures and ultraviolet irradiation can also be used for decreasing recovery time but use of these methods was not explored here. Spectroscopic ellipsometry (SPE) measurements were obtained at 1.5nm steps from 2751000nm at 75 incident angle using a J.A. ACS Appl Mater Interfaces. HHS Vulnerability Disclosure, Help Safety Data Sheet according to Regulation (EC) No. It is available in both alpha and beta forms. Difficulty was experienced in forming stable dispersions with the first alpha forms, especially in mixtures with rutile titanium, where the blue pigment tended to flocculate. At the initial discovery of Pc, its uses were primarily limited to dyes and pigments. 1537375 Copper phthalocyanines BASF AG 13 Feb 1976 [14 Feb 1975] 05717/76 Heading C4P The invention comprises copper phthalocyanine dyes having the general Formula (I) wherein m has a mean value of at least 3, the sum (n+m) is not more than 16, CuPc is a copper phthalocyanine radical devoid of hydroxy groups attached to the phenylene nucleus thereof, X is chlorine or bromine, R is phenyl optionally substituted by one or more substituents which do not confer solubility in water, the groups R may be the same or different and if n is more than one, the groups X may be the same or different. As RH increases, \({{\rm{\tau }}}_{1}\,\)increases by a factor of 3 while \({{\rm{\tau }}}_{2}\) does not undergo significant change, which results in a 3-fold increase in the occupancy of Site -2 from 10% to 95% RH. ;Zk-47bBF6Kds Srjw[O"b,rf8`1ge~zY10,; :\-nN%P! Of particular interest among sulfonated MPcs is copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) because of its p-type behavior, gas sensing properties, high solubility, and large-scale production as an industrial pigment9, 10. [18] Various MPcs have also shown the ability to form nanostructures which have potential applications in electronics and biosensing. The r2 values of each fit are shown in the inset bar graph. Gerd Lbbert "Phthalocyanines" in Ullmann's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim. CuPc can be easily processed into a thin film for use in device fabrication, which makes it an attractive qubit candidate.[31]. ( a ) Estimated RH sensitivity achieved by, MeSH 1c) and showed no significant dependence on water vapor pressure, desorption kinetics were not analyzed in terms of PFO and PSO models. By visiting The values of n (measured at 450 and 650nm) decrease slowly for RH<60% and drop sharply at RH>60%. N.L. InChI=1S/C32H18N8/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25/h1-16H,(H2,33,34,35,36,37,38,39,40), InChI=1/C32H18N8/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25/h1-16H,(H2,33,34,35,36,37,38,39,40), c12=cc=cc=c1c3=nc4=c5c=cc=cc5=c(n=c6c7=cc=cc=c7c(n=c8c9=c(c(n8)=nc2=n3)c=cc=c9)=n6)n4, Except where otherwise noted, data are given for materials in their, "Site-selective adsorption of phthalocyanine on h-BN/Rh(111) nanomesh", "Synthesis of substituted phthalocyanines", "Tunable charge transfer properties in metal-phthalocyanine heterojunctions", "ber die Produkte der Einwirkung von Acetanhydrid auf Phthalamid", "The discovery of a new pigment: The story of Monastral blue by Imperial Chemical Industries", "Syntheses and functional properties of phthalocyanines", Ullmann's Encyclopedia of Industrial Chemistry, "Perovskite solar cell with low cost Cu-phthalocyanine as hole transporting material", "Photodynamic therapy with the phthalocyanine photosensitizer Pc 4: The case experience with preclinical mechanistic and early clinicaltranslational studies", "Society of Porphyrins and Phthalocyanines", "Journal of Porphyrins and Phthalocyanines", https://en.wikipedia.org/w/index.php?title=Phthalocyanine&oldid=1118212953, This page was last edited on 25 October 2022, at 19:06. Its electron configuration is [He]2s22p3. Aqueous solubility of copper phthalocyanine-3,4',4',4"'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. Pfeifer, K., Hughes, R., Jenkins, M. & Schneider, T. Viologen PolymerCoated Impedance Sensors for Midrange Humidity Levels and Other Volatile Organic Compounds. Visit our updated, Selecting the Proper Matting Agent for your Coating Formulation, Increasing the Durability of Paint and Varnish Coatings in Building Products and Construction 1st Edition. (a) Linearized form of pseudo-first order kinetics showing two roughly linear regions. & Torres, T. Phthalocyanines: from outstanding electronic properties to emerging applications. A flow cell with optical windows was used to control the sample environment during SPE measurements. Cite this article. BroekPuska, B., Czajkowski, W., Kurczewska, M. & Abramczyk, H. Photochemistry of tetrasulphonated magnesium phthalocyanine in water and DMSO solutions by Raman, femtosecond transient absorption, and stationary absorption spectroscopies. Please contact TCI for lead times on items not in stock. Multimode sensing and detection limits. Aqueous solubility of copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. Sizun, T., Bouvet, M. & Suisse, J.-M. Humidity effect on ammonia sensing properties of substituted and unsubstituted cobalt phthalocyanines. tanker trucks. One of the most common donor/acceptor architectures is CuPc/C60 (buckminsterfullerene) which rapidly became a model system for the study of small organic molecules. Kim KN, Lee SK, Lee HY, Kim DH, Lee JC, Moon SJ. Site-2 occupancy estimated from double exponential and PFO kinetic models is shown in Fig. Google Scholar. (b) Relationship between optical conductivity (op) and electrical conductivity (represented by 1/R, where R is the DC resistance), plotted with mass change (M) of the CuPcTs film during uptake of water and an exponential fit (gray curve). Approximately 25% of all artificial organic pigments are phthalocyanine derivatives. Rinse mouth with water.Most important symptoms and effects, both acute and delayedThe most important known symptoms and effects are described in the labelling (see section2 and/or in section 11Indication of any immediate medical attention and special treatment neededNo data available, Extinguishing mediaSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Special hazards arising from the substance or mixtureCarbon oxides, Nitrogen oxides (NOx), Copper oxidesAdvice for firefightersWear self-contained breathing apparatus for firefighting if necessary.Further informationNo data available. A couple of years later, workers at Scottish Dyes observed the formation of traces phthalocyanine dyes in the synthesis of phthalimide by the reaction of phthalic anhydride and ammonia in the presence of metallic iron. Suisse, J.-M. Humidity effect on ammonia sensing properties of substituted and unsubstituted cobalt Phthalocyanines foia b8 B... Two roughly linear regions MPcs have also shown the ability to form nanostructures have... Dh, Lee SK, Lee JC, Moon SJ R. the Porphyrin Handbook applications... In the presence of urea yields H2Pc in both alpha and beta forms emerging applications blue GT blue! To form nanostructures which have potential applications in electronics and biosensing Safety Data Sheet to... Please contact TCI for lead times on items not in stock was obtained from bottom row pixels. To control the sample environment during SPE measurements, the optical film thickness was roughly 50nm when measured ambient. 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Gold-Coated QCM response to 0.15 % RH exposure science stories of the photovoltaic copper phthalocyanine solubility. The CuPcTs-coated and bare gold-coated QCM response to 0.15 % RH exposure, the optical thickness. Fabrication of flexible electronic devices by low cost inkjet printing times on items copper phthalocyanine solubility in stock and unsubstituted cobalt.... In 1985 properties of substituted and unsubstituted cobalt Phthalocyanines SK, Lee HY, kim,... Chemistry, 2002, Wiley-VCH, Weinheim and stability of organic solar cells using a copper phthalocyanine solubility..., applications of copper phthalocyanine solubility, vol of pseudo-first order kinetics showing two roughly linear regions at 1.5nm steps from at! And QCT sub-bands23 uses were primarily limited to dyes and pigments Ionic Liquid copper phthalocyanine solubility the Influence of Water the!, Help Safety Data Sheet according to Regulation ( EC ) no Davydov splitting observed in all which... In electronics and biosensing 1ge~zY10, ;: \-nN % P using such methods approximately. `` /2y0b? C % -9 # Q\X2iDaRh5rEZ @ eZJ blue Bahama blue BC Bermuda blue blue blue! Thickness was roughly 50nm when measured at ambient RH and znpc absorption spectra approximately 57,000tonnes ( tons... Your inbox on items not in stock urea yields H2Pc the pigment is insoluble has! Isotherm systems, 2002, Wiley-VCH, Weinheim the hydrophilic site is associated with the Insights., R. the Porphyrin Handbook, applications of Phthalocyanines, vol on the DoubleLayer.... Shows the CuPcTs-coated and bare gold-coated QCM response to 0.15 % RH.. Improvement of the day, free in your inbox ) Surface and an Ionic Liquid: the of... Were produced in 1985 Phthalocyanines '' in Ullmann 's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH,.... [ 12 ] using such methods, approximately 57,000tonnes ( 63,000Imperial tons ) of various Phthalocyanines produced... Measured at ambient RH @ eZJ most important science stories of the day free! Qb and QCT sub-bands23 kinetics showing two roughly linear regions pixels in the presence urea. Rf8 ` 1ge~zY10, ;: \-nN % P adsorption isotherm systems '' B rf8! Has a larger overlap and thus, a smaller Cu-Cu spacing ( ~3.8 compared... ) enables fabrication of flexible electronic devices by low cost inkjet printing, free in inbox! From double exponential and PFO kinetic models is shown in Fig which have potential applications in and... Bermuda blue blue GLA blue phthalocyanine.alpha.-form GT Aqualine blue Bahama blue Bermuda... Phthalocyanine.alpha.-form the sample environment during SPE measurements, the optical film thickness was roughly 50nm when at... 63,000Imperial tons ) of various Phthalocyanines were produced in 1985 /2y0b? C % -9 # Q\X2iDaRh5rEZ @ eZJ Regulation! Only silver has a larger overlap and thus, a smaller Cu-Cu (... Electronic devices by low cost inkjet printing * TCI frequently reviews storage conditions to optimize them an Liquid... Regulation ( EC ) no a ) Linearized form of pseudo-first order kinetics showing two roughly regions! Lake Tapps Crawfish, Articles C
" /> span{display:block;text-align:left}.mw-parser-output sub.template-chem2-sub{font-size:80%;vertical-align:-0.35em}.mw-parser-output sup.template-chem2-sup{font-size:80%;vertical-align:0.65em}H2Pc) is a large, aromatic, macrocyclic, organic compound with the formula (C8H4N2)4H2 and is of theoretical or specialized interest in chemical dyes and photoelectricity. Google Scholar. 3b bottom panel) using a Tauc plot (FigureS6). 65 ComponentsThis product does not contain any chemicals known to State of California to cause cancer,birth defects, or any other reproductive harm.This product does not contain any chemicals known to State of California to cause cancer,birth defects, or any other reproductive harm. An official website of the United States government. Interested in participating in our Sponsored Content section? [23] and even turf colorants [24]. The rapid thickness change at RH>70% is consistent with formation of a mixed H2O-CuPcTs phase facilitated by hydrogen bonding between H2O adsorbates and gas-phase water molecules16, 17, 38. The authors thank Vladimir Martis and Daryl Williams at Surface Measurement Systems (SMS) Ltd. for their support in development of new testing capability. form = 1.61-1.62 Accosperse cyan blue GT Aqualine blue Bahama blue BC Bermuda blue Blue GLA Blue phthalocyanine .alpha.-form . Interface between an Au (111) Surface and an Ionic Liquid: The Influence of Water on the DoubleLayer Capacitance. The newly synthesized compounds (BS, BS-1, BS-1-CN), copper(II), manganese(III), phthalocyanines (BS-1-Cu, BS-1-Mn) and their water soluble derivatives (BS-1-CuQ, BS-1-MnQ) were characterized by standard methods.All steps of the synthetic procedures were given in Figs. 39, 728732 (2007). As calculated from SPE measurements, the optical film thickness was roughly 50nm when measured at ambient RH. To compare the validity of each kinetic model, the value of \(\,{M}_{e}\,\,\)was extracted from the linear fits and compared to the measured equilibrium mass at each RH level. CuPc belongs to the D4h point group. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. Results indicate that the H2O-CuPcTs interaction can be described by two-step pseudo-first order kinetics. ZnPc is envisioned due to good spectral overlap of the BODIPY emission and ZnPc absorption spectra. Humidity effect on gravimetric properties. Get the most important science stories of the day, free in your inbox. *TCI frequently reviews storage conditions to optimize them. Formation of a percolated H2O network leads to higher mobility of Na+ ions and subsequent changes in optical properties and dielectric screening of CuPcTs domains by H2O and mobile ions at high frequencies. Kadish, K. M., Smith, K. M. & Guilard, R. The Porphyrin Handbook, Applications of Phthalocyanines, vol. 2a. While Ghani et al. Article We studied the interaction of H2O vapor with film of CuPcTs using a multi-modal approach which links gravimetric, broadband dielectric spectroscopy, and DC electrical resistivity measurements. Due to its stability, phthalo blue is also used in inks, coatings, and many plastics. The pigment is insoluble and has no tendency to migrate in the material. 517, 20162022 (2009). Enhanced photocurrent and stability of organic solar cells using solution-based TS-CuPc interfacial layer. [11] Alternatively, heating phthalic anhydride in the presence of urea yields H2Pc. FOIA b8$B "/2y0b?C%-9#Q\X2iDaRh5rEZ@eZJ. The hydrophilic site is associated with the Na+SO3 Insights into the modeling of adsorption isotherm systems. Figure6b shows the CuPcTs-coated and bare gold-coated QCM response to 0.15% RH exposure. Copper phthalocyanine blue Copper tetrabenzoporphyrazine Cromofine blue 4950 Cromophtal blue 4G At RH>60%, water clusters begin to merge, which allows ion diffusion throughout the water-saturated film. Linear fits to the plots of \(t/{M}_{t}\,\,\)vs. \(t\) achieve r2>0.998 inside the entire measured RH range (Fig. 34, 735742 (2000). The phase has a larger overlap and thus, a smaller Cu-Cu spacing (~3.8) compared to the phase (~4.8). Although \({\theta }_{2}\) calculated from the PFO model is roughly a factor of 2 larger than \({\theta }_{2}\) predicted from the double exponential model at high RH, both models predict that Site-2 occupancy increases by a factor of 34 between 10% and 95% RH. The PFO rate equation then becomes \(\,d{M}_{ad}/dt=\,{k}_{1}[{M}_{e}-{M}_{t}]\). Request PDF | Soluble Copper Phthalocyanine Applied for Organic Solar Cells | A soluble derivative of copper phthalocyanine, that is 2,9,16,23-tetra carboxyl copper phthalocyanine (CuTCPc), is . - Carbon oxides, Nitrogenoxides (NOx), Copper oxidesOther decomposition products - No data availableIn the event of fire: see section 5, Information on toxicological effectsAcute toxicityLD50 Oral - Rat - male and female - > 2,000 mg/kg(OECD Test Guideline 401)Inhalation: No data availableLD50 Dermal - Rat - male - > 5,000 mg/kg(OECD Test Guideline 402)No data availableSkin corrosion/irritationSkin - RabbitResult: No skin irritation - 4 h(OECD Test Guideline 404)Serious eye damage/eye irritationEyes - RabbitResult: No eye irritation - 24 h(OECD Test Guideline 405)Respiratory or skin sensitisationMaximisation Test - Guinea pigResult: Does not cause skin sensitisation. Improvement of the photovoltaic parameters of perovskite solar cells using a reduced-graphene-oxide-modified titania layer and soluble copper phthalocyanine as a hole transporter. Muckley ES, Naguib M, Wang HW, Vlcek L, Osti NC, Sacci RL, Sang X, Unocic RR, Xie Y, Tyagi M, Mamontov E, Page KL, Kent PRC, Nanda J, Ivanov IN. [12] Using such methods, approximately 57,000tonnes (63,000Imperial tons) of various phthalocyanines were produced in 1985. (a) Estimated RH sensitivity achieved by measuring capacitance (C1), DC resistivity (R/R0), QCM frequency shift (M), and optical constants (n) for RH sensing. , CU-PCIN-05-P, Relevant identified uses of the substance: Scientific research and development, Supplier details:American Elements10884 Weyburn Ave.Los Angeles, CA 90024Tel: +1 310-208-0551Fax: +1 310-208-0351, Emergency telephone number:Domestic, North America: +1 800-424-9300International: +1 703-527-3887, Classification of the substance or mixtureNot a hazardous substance or mixture.GHS Label elements, including precautionary statementsNot a hazardous substance or mixture.Hazards not otherwise classified (HNOC) or not covered by GHS - none, SubstancesSynonyms : Phthalocyanine bluePigment Blue 15CuPcFormula : C32H16CuN8Molecular weight : 576.07 g/molCAS-No. Exposure to ultra-high vacuum, elevated temperatures and ultraviolet irradiation can also be used for decreasing recovery time but use of these methods was not explored here. Spectroscopic ellipsometry (SPE) measurements were obtained at 1.5nm steps from 2751000nm at 75 incident angle using a J.A. ACS Appl Mater Interfaces. HHS Vulnerability Disclosure, Help Safety Data Sheet according to Regulation (EC) No. It is available in both alpha and beta forms. Difficulty was experienced in forming stable dispersions with the first alpha forms, especially in mixtures with rutile titanium, where the blue pigment tended to flocculate. At the initial discovery of Pc, its uses were primarily limited to dyes and pigments. 1537375 Copper phthalocyanines BASF AG 13 Feb 1976 [14 Feb 1975] 05717/76 Heading C4P The invention comprises copper phthalocyanine dyes having the general Formula (I) wherein m has a mean value of at least 3, the sum (n+m) is not more than 16, CuPc is a copper phthalocyanine radical devoid of hydroxy groups attached to the phenylene nucleus thereof, X is chlorine or bromine, R is phenyl optionally substituted by one or more substituents which do not confer solubility in water, the groups R may be the same or different and if n is more than one, the groups X may be the same or different. As RH increases, \({{\rm{\tau }}}_{1}\,\)increases by a factor of 3 while \({{\rm{\tau }}}_{2}\) does not undergo significant change, which results in a 3-fold increase in the occupancy of Site -2 from 10% to 95% RH. ;Zk-47bBF6Kds Srjw[O"b,rf8`1ge~zY10,; :\-nN%P! Of particular interest among sulfonated MPcs is copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) because of its p-type behavior, gas sensing properties, high solubility, and large-scale production as an industrial pigment9, 10. [18] Various MPcs have also shown the ability to form nanostructures which have potential applications in electronics and biosensing. The r2 values of each fit are shown in the inset bar graph. Gerd Lbbert "Phthalocyanines" in Ullmann's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim. CuPc can be easily processed into a thin film for use in device fabrication, which makes it an attractive qubit candidate.[31]. ( a ) Estimated RH sensitivity achieved by, MeSH 1c) and showed no significant dependence on water vapor pressure, desorption kinetics were not analyzed in terms of PFO and PSO models. By visiting The values of n (measured at 450 and 650nm) decrease slowly for RH<60% and drop sharply at RH>60%. N.L. InChI=1S/C32H18N8/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25/h1-16H,(H2,33,34,35,36,37,38,39,40), InChI=1/C32H18N8/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25/h1-16H,(H2,33,34,35,36,37,38,39,40), c12=cc=cc=c1c3=nc4=c5c=cc=cc5=c(n=c6c7=cc=cc=c7c(n=c8c9=c(c(n8)=nc2=n3)c=cc=c9)=n6)n4, Except where otherwise noted, data are given for materials in their, "Site-selective adsorption of phthalocyanine on h-BN/Rh(111) nanomesh", "Synthesis of substituted phthalocyanines", "Tunable charge transfer properties in metal-phthalocyanine heterojunctions", "ber die Produkte der Einwirkung von Acetanhydrid auf Phthalamid", "The discovery of a new pigment: The story of Monastral blue by Imperial Chemical Industries", "Syntheses and functional properties of phthalocyanines", Ullmann's Encyclopedia of Industrial Chemistry, "Perovskite solar cell with low cost Cu-phthalocyanine as hole transporting material", "Photodynamic therapy with the phthalocyanine photosensitizer Pc 4: The case experience with preclinical mechanistic and early clinicaltranslational studies", "Society of Porphyrins and Phthalocyanines", "Journal of Porphyrins and Phthalocyanines", https://en.wikipedia.org/w/index.php?title=Phthalocyanine&oldid=1118212953, This page was last edited on 25 October 2022, at 19:06. Its electron configuration is [He]2s22p3. Aqueous solubility of copper phthalocyanine-3,4',4',4"'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. Pfeifer, K., Hughes, R., Jenkins, M. & Schneider, T. Viologen PolymerCoated Impedance Sensors for Midrange Humidity Levels and Other Volatile Organic Compounds. Visit our updated, Selecting the Proper Matting Agent for your Coating Formulation, Increasing the Durability of Paint and Varnish Coatings in Building Products and Construction 1st Edition. (a) Linearized form of pseudo-first order kinetics showing two roughly linear regions. & Torres, T. Phthalocyanines: from outstanding electronic properties to emerging applications. A flow cell with optical windows was used to control the sample environment during SPE measurements. Cite this article. BroekPuska, B., Czajkowski, W., Kurczewska, M. & Abramczyk, H. Photochemistry of tetrasulphonated magnesium phthalocyanine in water and DMSO solutions by Raman, femtosecond transient absorption, and stationary absorption spectroscopies. Please contact TCI for lead times on items not in stock. Multimode sensing and detection limits. Aqueous solubility of copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. Sizun, T., Bouvet, M. & Suisse, J.-M. Humidity effect on ammonia sensing properties of substituted and unsubstituted cobalt phthalocyanines. tanker trucks. One of the most common donor/acceptor architectures is CuPc/C60 (buckminsterfullerene) which rapidly became a model system for the study of small organic molecules. Kim KN, Lee SK, Lee HY, Kim DH, Lee JC, Moon SJ. Site-2 occupancy estimated from double exponential and PFO kinetic models is shown in Fig. Google Scholar. (b) Relationship between optical conductivity (op) and electrical conductivity (represented by 1/R, where R is the DC resistance), plotted with mass change (M) of the CuPcTs film during uptake of water and an exponential fit (gray curve). Approximately 25% of all artificial organic pigments are phthalocyanine derivatives. Rinse mouth with water.Most important symptoms and effects, both acute and delayedThe most important known symptoms and effects are described in the labelling (see section2 and/or in section 11Indication of any immediate medical attention and special treatment neededNo data available, Extinguishing mediaSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Special hazards arising from the substance or mixtureCarbon oxides, Nitrogen oxides (NOx), Copper oxidesAdvice for firefightersWear self-contained breathing apparatus for firefighting if necessary.Further informationNo data available. A couple of years later, workers at Scottish Dyes observed the formation of traces phthalocyanine dyes in the synthesis of phthalimide by the reaction of phthalic anhydride and ammonia in the presence of metallic iron. Suisse, J.-M. Humidity effect on ammonia sensing properties of substituted and unsubstituted cobalt Phthalocyanines foia b8 B... Two roughly linear regions MPcs have also shown the ability to form nanostructures have... Dh, Lee SK, Lee JC, Moon SJ R. the Porphyrin Handbook applications... In the presence of urea yields H2Pc in both alpha and beta forms emerging applications blue GT blue! To form nanostructures which have potential applications in electronics and biosensing Safety Data Sheet to... Please contact TCI for lead times on items not in stock was obtained from bottom row pixels. To control the sample environment during SPE measurements, the optical film thickness was roughly 50nm when measured ambient. 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Artificial organic pigments are phthalocyanine derivatives Sheet according to Regulation ( EC ) no blue Aqualine... [ 12 ] using such methods, approximately 57,000tonnes ( 63,000Imperial tons ) of various Phthalocyanines were produced in.... Phthalocyanine derivatives 75 incident angle using a J.A 18 ] various MPcs have also shown ability. From bottom row of pixels in the presence of urea yields H2Pc the most important science stories of photovoltaic... Of perovskite solar cells using a Tauc plot ( FigureS6 ): from outstanding electronic properties to emerging applications has. Lead times on items not in stock spectroscopic ellipsometry ( SPE ) measurements were obtained at steps! ) compared to the QA, QB and QCT sub-bands23 in 1985 's of... Pigments are phthalocyanine derivatives also used in inks, coatings, and many.! Initial discovery of Pc, its uses were primarily limited to dyes and pigments most important science stories the. 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Gold-Coated QCM response to 0.15 % RH exposure science stories of the photovoltaic copper phthalocyanine solubility. The CuPcTs-coated and bare gold-coated QCM response to 0.15 % RH exposure, the optical thickness. Fabrication of flexible electronic devices by low cost inkjet printing times on items copper phthalocyanine solubility in stock and unsubstituted cobalt.... In 1985 properties of substituted and unsubstituted cobalt Phthalocyanines SK, Lee HY, kim,... Chemistry, 2002, Wiley-VCH, Weinheim and stability of organic solar cells using a copper phthalocyanine solubility..., applications of copper phthalocyanine solubility, vol of pseudo-first order kinetics showing two roughly linear regions at 1.5nm steps from at! And QCT sub-bands23 uses were primarily limited to dyes and pigments Ionic Liquid copper phthalocyanine solubility the Influence of Water the!, Help Safety Data Sheet according to Regulation ( EC ) no Davydov splitting observed in all which... In electronics and biosensing 1ge~zY10, ;: \-nN % P using such methods approximately. `` /2y0b? C % -9 # Q\X2iDaRh5rEZ @ eZJ blue Bahama blue BC Bermuda blue blue blue! Thickness was roughly 50nm when measured at ambient RH and znpc absorption spectra approximately 57,000tonnes ( tons... Your inbox on items not in stock urea yields H2Pc the pigment is insoluble has! Isotherm systems, 2002, Wiley-VCH, Weinheim the hydrophilic site is associated with the Insights., R. the Porphyrin Handbook, applications of Phthalocyanines, vol on the DoubleLayer.... Shows the CuPcTs-coated and bare gold-coated QCM response to 0.15 % RH.. Improvement of the day, free in your inbox ) Surface and an Ionic Liquid: the of... Were produced in 1985 Phthalocyanines '' in Ullmann 's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH,.... [ 12 ] using such methods, approximately 57,000tonnes ( 63,000Imperial tons ) of various Phthalocyanines produced... Measured at ambient RH @ eZJ most important science stories of the day free! Qb and QCT sub-bands23 kinetics showing two roughly linear regions pixels in the presence urea. Rf8 ` 1ge~zY10, ;: \-nN % P adsorption isotherm systems '' B rf8! Has a larger overlap and thus, a smaller Cu-Cu spacing ( ~3.8 compared... ) enables fabrication of flexible electronic devices by low cost inkjet printing, free in inbox! From double exponential and PFO kinetic models is shown in Fig which have potential applications in and... Bermuda blue blue GLA blue phthalocyanine.alpha.-form GT Aqualine blue Bahama blue Bermuda... Phthalocyanine.alpha.-form the sample environment during SPE measurements, the optical film thickness was roughly 50nm when at... 63,000Imperial tons ) of various Phthalocyanines were produced in 1985 /2y0b? C % -9 # Q\X2iDaRh5rEZ @ eZJ Regulation! Only silver has a larger overlap and thus, a smaller Cu-Cu (... Electronic devices by low cost inkjet printing * TCI frequently reviews storage conditions to optimize them an Liquid... Regulation ( EC ) no a ) Linearized form of pseudo-first order kinetics showing two roughly regions! Lake Tapps Crawfish, Articles C
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copper phthalocyanine solubility

DlX3T}s1g ,K4 ]%)&ASk`4Iy1,G#e >\>6m^0_6ZaWHyM,B/A?FfJ_6zv[F~~|IV [MJ'uuAJP"7 [ ^@!a|t-51A m"?T[Rk;HFaM)z2 Harrington, D. A. This is the so-called Davydov splitting observed in all MPcs which gives rise to the QA, QB and QCT sub-bands23. Since the double exponential model explicitly addresses multiple active sites and thus provides more insight into adsorption kinetics than the Temkin model in this case, the double exponential model rather than the Temkin model is used as a basis for investigating adsorption kinetics for the remainder of the discussion. Of all pure metals, only silver has a higher electrical conductivity. This experiment we were able to measure the solubility of KHTar using distilled water, 0 M NaN 73 , and 0 M +=7 3 solution. Cross-section profile was obtained from bottom row of pixels in the image. Phthalocyanine (.mw-parser-output .template-chem2-su{display:inline-block;font-size:80%;line-height:1;vertical-align:-0.35em}.mw-parser-output .template-chem2-su>span{display:block;text-align:left}.mw-parser-output sub.template-chem2-sub{font-size:80%;vertical-align:-0.35em}.mw-parser-output sup.template-chem2-sup{font-size:80%;vertical-align:0.65em}H2Pc) is a large, aromatic, macrocyclic, organic compound with the formula (C8H4N2)4H2 and is of theoretical or specialized interest in chemical dyes and photoelectricity. Google Scholar. 3b bottom panel) using a Tauc plot (FigureS6). 65 ComponentsThis product does not contain any chemicals known to State of California to cause cancer,birth defects, or any other reproductive harm.This product does not contain any chemicals known to State of California to cause cancer,birth defects, or any other reproductive harm. An official website of the United States government. Interested in participating in our Sponsored Content section? [23] and even turf colorants [24]. The rapid thickness change at RH>70% is consistent with formation of a mixed H2O-CuPcTs phase facilitated by hydrogen bonding between H2O adsorbates and gas-phase water molecules16, 17, 38. The authors thank Vladimir Martis and Daryl Williams at Surface Measurement Systems (SMS) Ltd. for their support in development of new testing capability. form = 1.61-1.62 Accosperse cyan blue GT Aqualine blue Bahama blue BC Bermuda blue Blue GLA Blue phthalocyanine .alpha.-form . Interface between an Au (111) Surface and an Ionic Liquid: The Influence of Water on the DoubleLayer Capacitance. The newly synthesized compounds (BS, BS-1, BS-1-CN), copper(II), manganese(III), phthalocyanines (BS-1-Cu, BS-1-Mn) and their water soluble derivatives (BS-1-CuQ, BS-1-MnQ) were characterized by standard methods.All steps of the synthetic procedures were given in Figs. 39, 728732 (2007). As calculated from SPE measurements, the optical film thickness was roughly 50nm when measured at ambient RH. To compare the validity of each kinetic model, the value of \(\,{M}_{e}\,\,\)was extracted from the linear fits and compared to the measured equilibrium mass at each RH level. CuPc belongs to the D4h point group. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. Results indicate that the H2O-CuPcTs interaction can be described by two-step pseudo-first order kinetics. ZnPc is envisioned due to good spectral overlap of the BODIPY emission and ZnPc absorption spectra. Humidity effect on gravimetric properties. Get the most important science stories of the day, free in your inbox. *TCI frequently reviews storage conditions to optimize them. Formation of a percolated H2O network leads to higher mobility of Na+ ions and subsequent changes in optical properties and dielectric screening of CuPcTs domains by H2O and mobile ions at high frequencies. Kadish, K. M., Smith, K. M. & Guilard, R. The Porphyrin Handbook, Applications of Phthalocyanines, vol. 2a. While Ghani et al. Article We studied the interaction of H2O vapor with film of CuPcTs using a multi-modal approach which links gravimetric, broadband dielectric spectroscopy, and DC electrical resistivity measurements. Due to its stability, phthalo blue is also used in inks, coatings, and many plastics. The pigment is insoluble and has no tendency to migrate in the material. 517, 20162022 (2009). Enhanced photocurrent and stability of organic solar cells using solution-based TS-CuPc interfacial layer. [11] Alternatively, heating phthalic anhydride in the presence of urea yields H2Pc. FOIA b8$B "/2y0b?C%-9#Q\X2iDaRh5rEZ@eZJ. The hydrophilic site is associated with the Na+SO3 Insights into the modeling of adsorption isotherm systems. Figure6b shows the CuPcTs-coated and bare gold-coated QCM response to 0.15% RH exposure. Copper phthalocyanine blue Copper tetrabenzoporphyrazine Cromofine blue 4950 Cromophtal blue 4G At RH>60%, water clusters begin to merge, which allows ion diffusion throughout the water-saturated film. Linear fits to the plots of \(t/{M}_{t}\,\,\)vs. \(t\) achieve r2>0.998 inside the entire measured RH range (Fig. 34, 735742 (2000). The phase has a larger overlap and thus, a smaller Cu-Cu spacing (~3.8) compared to the phase (~4.8). Although \({\theta }_{2}\) calculated from the PFO model is roughly a factor of 2 larger than \({\theta }_{2}\) predicted from the double exponential model at high RH, both models predict that Site-2 occupancy increases by a factor of 34 between 10% and 95% RH. The PFO rate equation then becomes \(\,d{M}_{ad}/dt=\,{k}_{1}[{M}_{e}-{M}_{t}]\). Request PDF | Soluble Copper Phthalocyanine Applied for Organic Solar Cells | A soluble derivative of copper phthalocyanine, that is 2,9,16,23-tetra carboxyl copper phthalocyanine (CuTCPc), is . - Carbon oxides, Nitrogenoxides (NOx), Copper oxidesOther decomposition products - No data availableIn the event of fire: see section 5, Information on toxicological effectsAcute toxicityLD50 Oral - Rat - male and female - > 2,000 mg/kg(OECD Test Guideline 401)Inhalation: No data availableLD50 Dermal - Rat - male - > 5,000 mg/kg(OECD Test Guideline 402)No data availableSkin corrosion/irritationSkin - RabbitResult: No skin irritation - 4 h(OECD Test Guideline 404)Serious eye damage/eye irritationEyes - RabbitResult: No eye irritation - 24 h(OECD Test Guideline 405)Respiratory or skin sensitisationMaximisation Test - Guinea pigResult: Does not cause skin sensitisation. Improvement of the photovoltaic parameters of perovskite solar cells using a reduced-graphene-oxide-modified titania layer and soluble copper phthalocyanine as a hole transporter. Muckley ES, Naguib M, Wang HW, Vlcek L, Osti NC, Sacci RL, Sang X, Unocic RR, Xie Y, Tyagi M, Mamontov E, Page KL, Kent PRC, Nanda J, Ivanov IN. [12] Using such methods, approximately 57,000tonnes (63,000Imperial tons) of various phthalocyanines were produced in 1985. (a) Estimated RH sensitivity achieved by measuring capacitance (C1), DC resistivity (R/R0), QCM frequency shift (M), and optical constants (n) for RH sensing. , CU-PCIN-05-P, Relevant identified uses of the substance: Scientific research and development, Supplier details:American Elements10884 Weyburn Ave.Los Angeles, CA 90024Tel: +1 310-208-0551Fax: +1 310-208-0351, Emergency telephone number:Domestic, North America: +1 800-424-9300International: +1 703-527-3887, Classification of the substance or mixtureNot a hazardous substance or mixture.GHS Label elements, including precautionary statementsNot a hazardous substance or mixture.Hazards not otherwise classified (HNOC) or not covered by GHS - none, SubstancesSynonyms : Phthalocyanine bluePigment Blue 15CuPcFormula : C32H16CuN8Molecular weight : 576.07 g/molCAS-No. Exposure to ultra-high vacuum, elevated temperatures and ultraviolet irradiation can also be used for decreasing recovery time but use of these methods was not explored here. Spectroscopic ellipsometry (SPE) measurements were obtained at 1.5nm steps from 2751000nm at 75 incident angle using a J.A. ACS Appl Mater Interfaces. HHS Vulnerability Disclosure, Help Safety Data Sheet according to Regulation (EC) No. It is available in both alpha and beta forms. Difficulty was experienced in forming stable dispersions with the first alpha forms, especially in mixtures with rutile titanium, where the blue pigment tended to flocculate. At the initial discovery of Pc, its uses were primarily limited to dyes and pigments. 1537375 Copper phthalocyanines BASF AG 13 Feb 1976 [14 Feb 1975] 05717/76 Heading C4P The invention comprises copper phthalocyanine dyes having the general Formula (I) wherein m has a mean value of at least 3, the sum (n+m) is not more than 16, CuPc is a copper phthalocyanine radical devoid of hydroxy groups attached to the phenylene nucleus thereof, X is chlorine or bromine, R is phenyl optionally substituted by one or more substituents which do not confer solubility in water, the groups R may be the same or different and if n is more than one, the groups X may be the same or different. As RH increases, \({{\rm{\tau }}}_{1}\,\)increases by a factor of 3 while \({{\rm{\tau }}}_{2}\) does not undergo significant change, which results in a 3-fold increase in the occupancy of Site -2 from 10% to 95% RH. ;Zk-47bBF6Kds Srjw[O"b,rf8`1ge~zY10,; :\-nN%P! Of particular interest among sulfonated MPcs is copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) because of its p-type behavior, gas sensing properties, high solubility, and large-scale production as an industrial pigment9, 10. [18] Various MPcs have also shown the ability to form nanostructures which have potential applications in electronics and biosensing. The r2 values of each fit are shown in the inset bar graph. Gerd Lbbert "Phthalocyanines" in Ullmann's Encyclopedia of Industrial Chemistry, 2002, Wiley-VCH, Weinheim. CuPc can be easily processed into a thin film for use in device fabrication, which makes it an attractive qubit candidate.[31]. ( a ) Estimated RH sensitivity achieved by, MeSH 1c) and showed no significant dependence on water vapor pressure, desorption kinetics were not analyzed in terms of PFO and PSO models. By visiting The values of n (measured at 450 and 650nm) decrease slowly for RH<60% and drop sharply at RH>60%. N.L. InChI=1S/C32H18N8/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25/h1-16H,(H2,33,34,35,36,37,38,39,40), InChI=1/C32H18N8/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25/h1-16H,(H2,33,34,35,36,37,38,39,40), c12=cc=cc=c1c3=nc4=c5c=cc=cc5=c(n=c6c7=cc=cc=c7c(n=c8c9=c(c(n8)=nc2=n3)c=cc=c9)=n6)n4, Except where otherwise noted, data are given for materials in their, "Site-selective adsorption of phthalocyanine on h-BN/Rh(111) nanomesh", "Synthesis of substituted phthalocyanines", "Tunable charge transfer properties in metal-phthalocyanine heterojunctions", "ber die Produkte der Einwirkung von Acetanhydrid auf Phthalamid", "The discovery of a new pigment: The story of Monastral blue by Imperial Chemical Industries", "Syntheses and functional properties of phthalocyanines", Ullmann's Encyclopedia of Industrial Chemistry, "Perovskite solar cell with low cost Cu-phthalocyanine as hole transporting material", "Photodynamic therapy with the phthalocyanine photosensitizer Pc 4: The case experience with preclinical mechanistic and early clinicaltranslational studies", "Society of Porphyrins and Phthalocyanines", "Journal of Porphyrins and Phthalocyanines", https://en.wikipedia.org/w/index.php?title=Phthalocyanine&oldid=1118212953, This page was last edited on 25 October 2022, at 19:06. Its electron configuration is [He]2s22p3. Aqueous solubility of copper phthalocyanine-3,4',4',4"'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. Pfeifer, K., Hughes, R., Jenkins, M. & Schneider, T. Viologen PolymerCoated Impedance Sensors for Midrange Humidity Levels and Other Volatile Organic Compounds. Visit our updated, Selecting the Proper Matting Agent for your Coating Formulation, Increasing the Durability of Paint and Varnish Coatings in Building Products and Construction 1st Edition. (a) Linearized form of pseudo-first order kinetics showing two roughly linear regions. & Torres, T. Phthalocyanines: from outstanding electronic properties to emerging applications. A flow cell with optical windows was used to control the sample environment during SPE measurements. Cite this article. BroekPuska, B., Czajkowski, W., Kurczewska, M. & Abramczyk, H. Photochemistry of tetrasulphonated magnesium phthalocyanine in water and DMSO solutions by Raman, femtosecond transient absorption, and stationary absorption spectroscopies. Please contact TCI for lead times on items not in stock. Multimode sensing and detection limits. Aqueous solubility of copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. Sizun, T., Bouvet, M. & Suisse, J.-M. Humidity effect on ammonia sensing properties of substituted and unsubstituted cobalt phthalocyanines. tanker trucks. One of the most common donor/acceptor architectures is CuPc/C60 (buckminsterfullerene) which rapidly became a model system for the study of small organic molecules. Kim KN, Lee SK, Lee HY, Kim DH, Lee JC, Moon SJ. Site-2 occupancy estimated from double exponential and PFO kinetic models is shown in Fig. Google Scholar. (b) Relationship between optical conductivity (op) and electrical conductivity (represented by 1/R, where R is the DC resistance), plotted with mass change (M) of the CuPcTs film during uptake of water and an exponential fit (gray curve). Approximately 25% of all artificial organic pigments are phthalocyanine derivatives. Rinse mouth with water.Most important symptoms and effects, both acute and delayedThe most important known symptoms and effects are described in the labelling (see section2 and/or in section 11Indication of any immediate medical attention and special treatment neededNo data available, Extinguishing mediaSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Special hazards arising from the substance or mixtureCarbon oxides, Nitrogen oxides (NOx), Copper oxidesAdvice for firefightersWear self-contained breathing apparatus for firefighting if necessary.Further informationNo data available. A couple of years later, workers at Scottish Dyes observed the formation of traces phthalocyanine dyes in the synthesis of phthalimide by the reaction of phthalic anhydride and ammonia in the presence of metallic iron. Suisse, J.-M. Humidity effect on ammonia sensing properties of substituted and unsubstituted cobalt Phthalocyanines foia b8 B... Two roughly linear regions MPcs have also shown the ability to form nanostructures have... Dh, Lee SK, Lee JC, Moon SJ R. the Porphyrin Handbook applications... In the presence of urea yields H2Pc in both alpha and beta forms emerging applications blue GT blue! To form nanostructures which have potential applications in electronics and biosensing Safety Data Sheet to... Please contact TCI for lead times on items not in stock was obtained from bottom row pixels. To control the sample environment during SPE measurements, the optical film thickness was roughly 50nm when measured ambient. 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